p-Toluenesulfonyl cyanide

REF : 248835-5G
Marca : Sigma-Aldrich
Descrição :p-Toluenesulfonyl cyanide technical grade, 95%
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Descrição detalhada : p-Toluenesulfonyl cyanide is an electron-deficient nitrile. It undergoes hetero-Diels-Alder reaction with silyl enol ether of cyclohexenone to yield hydrolytically sensitive [4+2] adduct. It also undergoes facile [2+3] cycloaddition reaction with azides to form 5-sulfonyl tetrazoles. p-Toluenesulfonyl cyanide also reacts with alcohols in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) or 1,4-diazabicyclo[2.2.2]octane (DABCO) to yield sulfinates.
Sinónimos : p-Tolylsulfonyl cyanide; Tosyl cyanide
Fórmula molecula r: CH3C6H4SO2CN
Armazenamento : 2-8C
Embalagem : 1X5G